ACS News Service Weekly PressPac: October 1, 2008

• New material could speed development of hydrogen powered vehicles
• Playing pinball with atoms
• Potentially toxic flame retardants highest in California households
• Fungus fights air pollution by removing sulfur from crude oil
• Water shortages pose challenges and opportunities for industry

Researchers in Greece report design of a new material that almost meets the U.S. Department of Energy (DOE) 2010 goals for hydrogen storage and could help eliminate a key roadblock to practical hydrogen-powered vehicles. Their study on a way of safely storing hydrogen, an explosive gas, is scheduled for the Oct. 8 issue of ACS’ Nano Letters, a monthly journal.

Georgios K. Dimitrakakis, Emmanuel Tylianakis, and George E. Froudakis note that researchers long have sought ways of using carbon nanotubes (CNTs) to store hydrogen in fuel cell vehicles. CNTs are minute cylinders of carbon about 50,000 times thinner than the width of a human hair. Scientists hope to use CNTs as miniature storage tanks for hydrogen in the coming generation of fuel cell vehicles.

In the new study, the researchers used computer modeling to design a unique hydrogen-storage structure consisting of parallel graphene sheets — layers of carbon just one atom thick — stabilized by vertical columns of CNTs. They also added lithium ions to the material’s design to enhance its storage capacity. The scientists’ calculations showed that their so-called “pillared graphene” could theoretically store up to 41 grams of hydrogen per liter, almost matching the DOE’s target (45 grams of hydrogen per liter) for transportation applications. “Experimentalists are challenged to fabricate this material and validate its storage capacity,” the researchers note. — MTS

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In what may be an unintended consequence of efforts to make furniture safer and less flammable, residents of California have blood levels of potentially toxic flame retardants called PBDEs at levels nearly twice the national average, scientists from Massachusetts and California are reporting. Their study, the first to examine regional variations in PBDE levels in household dust and blood within the U.S., is scheduled for posting online Oct. 1 by ACS’ semi-monthly journal Environmental Science & Technology.

In the new study, Ami Zota and colleagues note that PBDEs (polybrominated diphenyl ethers) are widely used as flame retardants in upholstered furniture and electronics. The materials are released into the environment as dust particles, where they can accumulate in homes as well as human blood and tissue. Although their exact effects in humans are unclear, studies in animals suggest that PBDEs may cause thyroid, developmental, and reproductive problems. Since California has among the most stringent furniture flammability standards, the researchers suspected that state residents may have higher levels of PBDE dust exposure than others in the United States.

To find out, the scientists compared data on PBDE concentrations in house dust from 49 California homes with concentrations reported from 120 Massachusetts homes and several other areas. The researchers also compared data on blood levels of PBDEs in California residents to blood levels in residents of other regions. They found that PBDE levels in California homes were four to 10 times higher than other U.S. areas. They also found that blood levels of some PBDEs were significantly higher in California residents than the rest of the country. “These findings raise concern about pending regulations and performance standards that encourage the widespread use of chemical flame retardants, which are toxic or whose safety is uncharacterized,” the article states. — MTS and AD

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Just as a credit crunch is reshaping the global economic landscape, an often-unheralded shortage of clean water is confronting business and industry with a range of profound new challenges and opportunities, according to an article scheduled for the October 6 issue of Chemical & Engineering News, ACS’ weekly news magazine.

The cover story, written by C&EN Senior Business Editor Melody Voith, points out that big industrial companies, such as Dow Chemical, General Electric, Nalco, and Ashland, must manage day-to-day operations in ways that conserve and reuse water. Once regarded as a cheap and inexhaustible resource, clean water increasingly is in short supply around the world, Voith explains, noting that lack of clean water is “a growing risk” to industry.

“There is just no replacement for good, clean water — and it is getting harder to come by,” Voith states. At the same time, companies that supply water purification and conservation technology are taking advantage of new opportunities. The articles explain how companies are investing in new technologies to meet the evolving demand for water treatment chemicals, services, and equipment.

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• Have a Ball with National Chemistry Week Oct. 19 - 25

Activities will be held in communities around the United States Oct. 19-25 during National Chemistry Week, the American Chemical Society’s annual showcase of chemistry’s central role in everyday life. The theme will be “Having a Ball with Chemistry,” emphasizing the role chemistry plays in fitness and athletics. Thousands of students will learn about chemistry’s role in providing new materials and technology to improve athletic equipment and performance, and the importance of nutrition and maintaining an active lifestyle. For more information, including the location of local NCW events, please visit http://www.chemistryweek.org.

• Press releases, chat room sessions, and more from ACS' 236th National Meeting

It's never too late to explore a treasure trove of news sources, background material and story ideas available from the ACS' latest National Meeting, which was held in Philadelphia from August 17-21, 2008. Reporters can view press releases, search an archive with abstracts of more than 9,000 scientific presentations and hundreds of non-technical summaries of those presentations, and access other resources at: www.eurekalert.org/acsmeet.php.

The ACS Office of Public Affairs also offers recorded video versions of its national meeting "chat room" briefings and accompanying chat transcripts by going to http://www.ustream.tv/channel/acslive. To use this site, you must first register with Ustream.tv by going to http://ustream.tv/sign-up-step-1. It's free and only takes a minute or two to sign up. To view the archived chat room sessions, proceed by clicking the "Login" button at the top right of the Ustream window and then selecting "Past Clips." Please note that Ustream requires the latest version of Adobe Flash, which can be downloaded without charge at http://www.adobe.com/products/flashplayer.

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