Trichlorofluoromethane

July 22, 2019
I’m an atmospheric ozone destroyer that hasn’t yet been eliminated.
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Image of Trichlorofluoromethane 3D Image of Trichlorofluoromethane

Trichlorofluoromethane, also known as CFC-11 and Freon 11, is a refrigerant, aerosol propellant, and foam-blowing agent. It is unusual in that its boiling point is at normal ambient temperature and pressure, so it can be handled as a liquid or gas. It is often described as having an “ethereal” (i.e., etherlike) odor.

Once the world’s most widely used refrigerant, CFC-11 came under attack in the 1980s because it was discovered that CFC-11 and other chlorofluorocarbons deplete the ozone layer in Earth’s atmosphere. Countries that subscribed to the Montreal Protocol of 1987 agreed to a moratorium on its production, with full cessation by 2010. The United States stopped making it at the end of 1995.

The atmospheric concentration of CFC-11 gradually decreased from 1995 to 2014, when it began to rise again. Recently, atmospheric monitoring by S. Park at Kyungpook National University (Daegu, South Korea) and collaborators in six countries revealed that significant CFC-11 emissions are coming from northeast China despite the country’s efforts to clamp down on manufacturers. According to one team member, “They’re producing [CFC-11] in serious quantities. We hope this [study] provides another piece of information [China] can use to tackle this problem.”

Trichlorofluoromethane hazard information

GHS classification*: acute toxicity, dermal, category 4
H312—Harmful in contact with skin Chemical Safety Warning

*Globally Harmonized System of Classification and Labeling of Chemicals. Explanation of pictograms.

Trichlorofluoromethane fast facts

CAS Reg. No. 75-69-4
Empirical formula CCl3F
Molar mass 137.37 g/mol
Appearance Colorless liquid or gas
Boiling point 23.7 ºC
Water solubility 1.1 g/L

MOTW update

Sulfoxaflor was the Molecule of the week for October 5, 2015. It is a central nervous system insecticide that is toxic to honeybees. In 2015, a federal appeals court overturned its US Environmental Protection Agency registration. But earlier this month, in a controversial move, EPA reauthorized its use on several crops. Will more legal action follow?

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