"Recycling Rare Earth Elements from Industrial Wastewater with Flowerlike Nano-Mg(OH)2"
ACS Applied Materials & Interfaces
Many of today’s technologies, from hybrid car batteries to flat-screen televisions, rely on materials known as rare earth elements (REEs) that are in short supply, but scientists are reporting development of a new method to recycle them from wastewater. The process, which is described in a study in the journal ACS Applied Materials & Interfaces, could help alleviate economic and environmental pressures facing the REE industry.
Zhang Lin and colleagues point out that REEs, such as terbium — a silvery metal so soft it can be cut with a knife — behave in unique ways as super magnets, catalysts or superconductors. That makes them irreplaceable in many of today’s tech gadgets and machines. Market watchers expect global demand to rise to at least 185,000 tons by 2015. Although some of these elements are actually plentiful, others are indeed in short supply. According to reports, terbium and dysprosium supplies may only last another 30 years. Attempts so far to recycle them from industrial wastewater are expensive or otherwise impractical. A major challenge is that the elements are typically very diluted in these waters. The team knew that a nanomaterial known as nano-magnesium hydroxide, or nano-Mg(OH)2, was effective at removing some metals and dyes from wastewater. So they set out to understand how the compound worked and whether it would efficiently remove diluted REEs, as well.
To test their idea, they produced inexpensive nano-Mg(OH)2 particles, whose shapes resemble flowers when viewed with a high-power microscope. They showed that the material captured more than 85 percent of the REEs that were diluted in wastewater in an initial experiment mimicking real-world conditions. “Recycling REEs from wastewater not only saves rare earth resources and protects the environment, but also brings considerable economic benefits,” the researchers state. “The pilot-scale experiment indicated that the self-supported flower-like nano-Mg(OH)2 had great potential to recycle REEs from industrial wastewater.”
The authors cite funding from the National Basic Research Program of China, the Outstanding Youth Fund, the National Natural Science Foundation of China, Fund of Fujian Key Laboratory of Nanomaterials and the Knowledge Innovation Program of the Chinese Academy of Sciences.